An Informational Brief on Polymer Machining

 

Known for its ease of machining, coloring and adaptability to additives, ABS is a versatile performance thermoplastic.  While it may be used in household toys, it is also used for mission critical applications like electrical insulators and automotive interior and exterior parts.

 

AIP has over 37 years of experience machining complex components from thermoplastics like Acrylonitrile Butadiene Styrene (ABS).  In this insightful technical brief, we will discuss what goes into machining ABS and how it differs from other manufacturing options such as metal machining, injection molding, and 3D printing.

 

Properties of ABS

 

Machinists should keep data on the properties of the thermoplastics they use.  This aids in selecting the right material for a project.  Also, it helps determine if the material is a good candidate for the end-use.  Below are some of the key characteristics of Acrylonitrile Butadiene Styrene (ABS):

 

Key Properties

  • Impact resistance
  • Chemical resistance
  • Ideal electrical insulator with added moisture resistance
  • Good strength and stiffness
  • Platable grades
  • Excellent aesthetic qualities
  • Colorable
  • Various gloss levels (Matte to High Gloss)

 

Description

ABS is one of the most common thermoplastic polymers manufactured. It is relatively cheap compared to other performance thermoplastics, such as, PEEK or VESPEL.

 

It provides good mechanical properties, including, impact resistance, toughness and rigidity compared to other common polymers. It is also easy to modify with additives to improve any of its properties. It is often a polymer of choice where aesthetics and color are concerned, since its natural color is translucent ivory to white. Pigments and additives are often added to this resin to improve the qualities based on the project needs.

 

Two major categories could be ABS for extrusion and ABS for injection molding, then high and medium impact resistance. Generally, ABS would have useful characteristics within a temperature range from −20 to 80 °C (−4 to 176 °F). As an amorphous polymer, it does not have a true melting point.

 

The table below displays an overview of the material properties, units and values for machining ABS:

 

Material Property Units Value
Tensile Elongation at Break @73 F % 20
Flexural Modulus of Elasticity @ 73 F psi 340000
Tensile Modulus of Elasticity @ 73 F psi 346000
Flexural Strength @ 73 F psi 9300
Specific Gravity @73 F ASTM D792 1.04
Tensile Strength @73 F, (ult)/(yld) psi 5500 (ult)
Notched Izod Impact @73 F ft-lb/in of notch 7.0
Heat Deflection Temperature @ 264 psi F 220
Flammability Rating UL94 HB(6.10mm)
Coefficient of Linear Thermal Expansion @73 F in/in/F 5.2E-05
Dielectric Strength, Short Term Volts/mil 450
Water Absorption, Immersion, 24 hours
Water Absorption, Saturation
% by weight
% by weight
0.30
0.70

 

Applications of ABS

 

ABS is mostly found in a wide variety of consumer products. Some of which include – Legos®, recorders and other musical instruments, golf club heads, household vacuums, and so on. ABS is a household staple for many consumer goods.

 

It also finds several end-use applications in the industrial sector. Applications include – automotive trim and components, inhalers, tendon prostheses, drug-delivery system tracheal tubes, enclosures for electrical and electronic assemblies, protective headgear and more.

 

Common Applications

  • Structural components
  • Automotive interior and exterior parts
  • Medical devices
  • Electrical components and assemblies
  • Toys
  • Housings/covers
  • Kitchen appliances

 

AIP Machining Capabilities: Unrivaled Expertise

 

Our close ties with the industry’s leading plastics manufacturers give us even further insight and access to technical help in material selection, sizing and manufacturing procedures. If you are looking for a trademarked material for your project, we have a host of material bases available for expert machining. Whatever your application, our machinists can help you in material selection, sizing and manufacturing techniques from concept to completion.

 

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Machining ABS

 

Annealing ABS

As with any CNC machined part, annealing and stress-relieving is crucial to the machining process. Coolants, lubricants and trained procedures prevent cracking and crazing in a precision machined component. We recommend slow heating and cooling during the annealing process of thermoplastics. This reduces the chances of these stresses occurring from the heat generating during machining polymers like ABS. Our AIP machinists use computer controlled annealing ovens for the highest quality precision temperatures and time control. .

 

Machining ABS

PVC can be injection molded, extruded or thermoformed.  At AIP, we CNC machine compounded PVC.  For the best results, use sharp tools, avoid excessive clamping and cutting forces and use coolants to prevent overheating.  We recommend non-aromatic, water-soluble coolants because they are most suitable for ideal surface finishes and close tolerances. These include pressurized air and spray mists. Coolants also preserve and extend the life of tools.  These guidelines are general and are not a substitute for a conversation with your machinist.  For further information, speak to a CNC machinist at AIP to get specific machining information on PVC and other performance thermoplastics.

 

Although it is often blow molded, ABS can be CNC machined and milled for precision parts. ABS is manufactured in a variety of grades, but for precision machining of ABS structural parts, it is recommended to use Machine Grade ABS. For the best results, use sharp tools, avoid excessive clamping and cutting forces and use coolants to prevent overheating. We recommend non-aromatic, water-soluble coolants because they are most suitable for ideal surface finishes and close tolerances. These include pressurized air and spray mists. Coolants have the additional benefit of extending tool life as well.

 

Some companies machine both metals and plastics, which has detrimental outcomes for machined polymer products. Many past experiences have shown parts going to customer without cracks, only to develop surface cracks and warping over time due to exposure to metal machine shop fluids. Be sure to use a facility like AIP that only machines polymers.

 

Preventing Contamination

Contamination is a serious concern when machining polymer components for technically demanding industries such as aerospace and medical sciences. To ensure the highest level of sanitation down to the sub-molecular level, AIP Precision Machining designs, heat-treats, and machines only plastics with any sub-manufactured metalwork processed outside our facility. This allows us to de-risk the process from metallic cross contamination.

 

ABS Machining Guide: Supportive Information

 

Quality Assurance Certifications
Miscellaneous Materials

 

How will the heat from your machining project affect your project? Make sure to talk to your machinist about the CLTE of your machined part.

 

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What is HDT?

 

The Heat Deflection Temperature (HDT), or Heat Distortion Temperature, is a measure of a polymer’s resistance to alteration under a given load at an elevated temperature.  It is also known as the ‘deflection temperature under load’ (DTUL) or ‘heat deflection temperature under load (HDTUL)’.  Basically, it tests the stiffness of a material as the temperature increases.

 

It is the temperature at which a polymer test bar will be bent at 0.25 mm under a given weight.  It is one of the two basic test methods for assigning a value to the performance of a plastic at high temperature.  The 0.25mm value is arbitrary and does not have any significant meaning.

 

Why is HDT significant?

 

As with any machined part, during the design phase, it is critical for a machinist to know how a material will react to heat produced while machining occurs.  Tools produce heat when they come in contact with materials and plastics have a tendency to move with heat.  In order to get a finished product with the right dimensions and tolerances, it is important to understand the heat deflection temperature of a given polymer.

 

Other reasons include:

  • HDT represents a value which can be used to compare different materials with each other
  • It is applied in product design, engineering and manufacture of products using thermoplastic components
  • A higher HDT temperature means a faster molding process in injection molding processes

 

Tests to Measure Heat Deflection Temperatures of Plastics

 

The American Society for Testing and Materials, or ASTM, standard for measuring HDT is called ASTM D 648; this standard is equivalent to the ISO 75.

 

The two common loads used in heat deflection testing are:

  • 0.46 MPa (67 psi) – this load is usually for softer grades of plastic like polyethylene (PE) or LDPE.
  • 1.8 MPa (264 psi) – this load is used for more durable grades of plastic like PEEK or polycarbonate (PC).

 

There are tests performed at higher loads such as 5.0 MPa (725 psi) or 8.0 MPa (1160 psi), but we won’t discuss them in this brief.

 

Limitations that are associated with the determination of the HDT is that the sample is not thermally isotropic and, in thick samples in particular, will contain a temperature gradient.

 

During the ASTM D 648 test, a testing rod made of the selected polymer is placed on an apparatus like the one in the diagram below.

 

 

 

Source: SEKISUI Polymer Innovation
 

The bar is molded a specific thickness and width.  The sample is then submerged in oil while the temperature incrementally increases (usually about 2 oC per minute).  The constant applied force, or load, is pressed to the midpoint of the test bar.  The temperature at which a bar of material is deformed 0.25mm is recorded as the HDT.

 

HDT at 1.8 Mpa (264 psi) Values for Common Polymers

 

 

Polymer Name Min Value (o C) Max Value (o C)
ABS – Acrylonitrile butadiene styrene 88 100
PA – Nylon Polyamide, 66 30% Glass Fiber 230 255
PAI – Polyamide-Imides (TORLON) 275 280
PBI – Polybenzimidazole (CELAZOLE) 426.6
PC – Polycarbonate, high heat 140 180
PE – Polyethylene, 30% glass fiber 121 121
PEEK – Polyetheretherketone 150 160
PEI – Polyetherimide (ULTEM) 190 200
PP – Polypropylene (30-40% Glass fiber-reinforced) 125 140
PP – Polypropylene Homopolymer/Copolymer 50 60
PS – Polystyrene, high heat 85 100
PSU – Polysulfone 160 174
PTFE – Polytetrafluorethylene 45 50
PVC – Polyvinyl chloride, rigid 54 75
PVDF – Polyvinylidene fluoride (KYNAR) 50 125

 

Factors That Influence HDT

 

The HDT gives a short-term performance under load at elevated temperatures for a polymer by measuring the effect of temperature on stiffness.  Yet, this is only an estimate and should not be used to predict how the final part or component will perform.

 

Other factors will significantly influence the final thermal performance of an application.

 

These factors include:

  • The time of exposure to elevated temperature
  • The rate of temperature increase
  • The part geometry

 

The HDT measure for a specific polymer grade also depends on the base resin and the presence of reinforcing agents, fillers or plasticizers.

 

For instance, in the chart above, the homopolymer or copolymer of polypropylene has a HDT value range of 50-60 oC. Compare that value to the 30-40% glass-fiber reinforced grade of polypropylene, which is more than double the temperature (125-140 oC).  A factor like this would influence the material choice for a designer wanting to use polypropylene for the end use product.

 

A combination of additives will always have a different effect on the HDT and the performance of a polymer overall.

 

  • Reinforced and filled grades have a higher HDT (harder and stiffer under the heat)
  • Plasticizers decrease HDT by making the polymer softer and more flexible

 

AIP:  Unmatched Precision.  Unrivaled Experience

 

Data charts can give you the heat deflection temperature, glass transition and other values.  However, a chart can give a general idea of these values, but an entire data set with the curve of a material is the best way to determine the right material for your project.

 

Be sure to work with a plastics machining company that can provide you a wide range of data on the HDT and other values of polymers and composites.  Your machinist will be able to give you a detailed response on how the heat deflection temperature will affect your project’s design and functionality.  Talk to one our engineers at AIP about your project design, and we will work with you to provide unrivaled expertise from your project’s initial concept to completion.

 

Supporting Materials

Certifications and Technical Data Resources

 

Learn more about the material properties we consider when
working on a precision plastics machining project.

 

Read our blog on the CUT of Polymers
 

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