An Informational Brief on Polymer Machining

 

Kynar®, Polyvinylidene Difluoride (PVDF) is a specialty fluoropolymer thermoplastic known for its ease of processing and its versatility in a variety of applications.  PVDF’s manufacturing not only ensures durability in its utility, but also delivers an innate resistance to acids, bases, high temperatures, and solvents.  Harsh industrial environments are no match for PVDF parts, which is why it is commonly used in environments requiring extreme resistance to a broad range of chemicals.

 

Additional demand for fluoropolymers like Kynar® PVDF is driven by the increasing trend of specialized, small-batch production for customized parts and components. Companies developing prototypes find it extremely convenient to have access to a fluoropolymer part manufacturer such as AIP.  Furthermore, AIP’s experience with custom-engineering plastics ensures our customers’ evolving needs are always met with the same level of innovation and excitement for creating new ways to deliver value in fluoropolymer applications.

 

Our latest machining guide discusses what goes into machining PVDF and how its considerations differ from other manufacturing options such as metal machining, injection molding, and 3D printing.

 

How does AIP approach PVDF and its machining process? To start, we’ll explain the difference between machining PVDF, a thermoplastic, and machining thermosets.

 

Machining Thermoplastics vs Thermosets

 

We’ve already said that PVDF is a thermoplastic, but what does that mean exactly?

 

All polymers can more or less be divided into two categories: thermoplastics and thermosets. The main difference between them is how they react to heat. Thermoplastics like PVDF, for example, melt in heat, while thermosets remain “set” once they’re formed. Understanding the technical distinction between these types of materials is essential to CNC machining them properly.

 

What type of thermoplastic is PVDF in particular? PVDF is a semi-crystalline, high purity engineering thermoplastic, meaning its molecular structure is highly ordered.

 

Properties & Grades of Machined Kynar® (PVDF)

 

As a thermoplastic, Kynar® PVDF offers industrial-grade resistance to pH changes due to varying thermal conditions, as well as solvent-resisting capabilities. This can be an advantage in petrochemical industries where fluoropolymer parts are in contact with or exposed to bursts of gases, oil or detergents.

 

It should also be noted that Kynar® PVDF is known for its high degree of crystallinity, which results in a stronger and strain-resisting component. Add to that a natural resistance to fungus, ozone and weather, which makes Kynar® PVDF a great fluoropolymer for coatings and manufactured parts exposed to the elements.

 

Finally, adding to its versatile performance in industrial environments, Kynar® PVDF provides excellent resistance to nuclear radiation, allowing it to be used in both Power Generation and military applications.

 

AIP offers a range of Kynar® and PVDF grades that provide different strength, thermal stability, and corrosion resistance and can help you select the best grade of PVDF for your application..

 

Machining Kynar® (PVDF)

 

Annealing PVDF

 

The process of annealing and stress-relieving PVDF reduces the likelihood of surface cracks and internal stresses occurring in the material. Post-machining annealing also helps to reduce stresses that could potentially contribute to premature failure.

 

Machining Kynar

 

PVDF offers ease of machining and tight tolerances due to its inherent strength, toughness and dimensional stability. Machining PVDF isn’t too different from machining metals as a result of this; pretend you’re machining brass. Unlike metal, though, PVDF (like all thermoplastics) will deform if you hold it too tightly as it yields easily.

 

We generally recommend Tungsten Carbide Alloy Tooling. Also, keep the part very cool and support it well.

 

We also suggest non-aromatic, air-based coolants to achieve optimum surface finishes and close tolerances. Coolants have the additional benefit of extending tool life as well.

 

Case in point, Kynar® PVDF can be manufactured into industrial equipment components that may include piping and tubing, valves, tanks, nozzles, and fittings—among many other formats. It can also be combined with other materials, helping customers innovate and create new product classes with utility that exceeds its original applications.

 

Preventing Contamination

 

Contamination is a serious concern when machining polymer components for technically demanding industries such as aerospace sciences. To ensure the highest level of sanitation down to the sub-molecular level, AIP Precision Machining designs, heat-treats and machines only plastics, with any sub-manufactured metalwork processed outside our facility.  This allows us to de-risk the process from metallic cross contamination.

 

Kynar® (PVDF) Machining Guide: Supportive Information

 

Chemical Resistant Materials

 

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An Informational Brief on Polymer Machining

 

Vespel Polyimide (PI) is a high-performance polymer frequently machined for end-use in aerospace, semiconductor and transportation technology. This material thrives in extreme environments with high strength, chemical resistance, high temperatures, and a low coefficient of friction. It also has impressive sealing and wear properties.

Our latest machining guide discusses what goes into machining Vespel and how its considerations differ from other manufacturing options such as metal machining, injection molding, and 3D printing.

How does AIP approach Vespel and its machining process? To start, we’ll explain the difference between machining PI, a thermoplastic, and machining thermosets.

 

Machining Thermoplastics vs Thermosets

 

We’ve already said that Vespel is a thermoplastic, but what does that mean exactly?

All polymers can more or less be divided into two categories: thermoplastics and thermosets. The main difference between them is how they react to heat. Thermoplastics like Vespel, for example, melt in heat, while thermosets remain “set” once they’re formed. Understanding the technical distinction between these types of materials is essential to CNC machining them properly.

What type of thermoplastic is Vespel in particular? PI is a semi-crystalline engineering thermoplastic, meaning its molecular structure is highly ordered.

 

Properties & Grades of Machined Vespel

 

Combining heat resistance, lubricity, dimensional stability, chemical resistance and creep resistance, Vespel works well in hostile and extreme environmental conditions. Vespel is able to overcome severe sealing and wear. As we mentioned before, these properties allow Vespel to be commonly machined for semiconductors and transportation applications.

Unlike most plastics, Vespel doesn’t produce significant outgassing, even at high temperatures. This makes it useful for lightweight heat shields and crucible support. Vespel also performs well in vacuum applications and extremely low cryogenic temperatures. However, it does absorb a small amount of water, which results in a longer pump time while placed in a vacuum.

Although there are polymers that surpass individual properties of this polyimide, the combination of these factors is Vespel’s primary advantage.

We regularly machine various grades of Vespel at AIP Precision Machining, including the Vespel SP and Vespel SCP family of products from DuPont. The former group is known for their durability and exceptional thermal resistance, while the latter is known for its mechanical properties and thermal stability.

 

Machining Vespel

 

Annealing Vespel

 

The process of annealing and stress-relieving Vespel reduces the likelihood of surface cracks and internal stresses occurring in the material. Post-machining annealing also helps to reduce stresses that could potentially contribute to premature failure.

 

Machining Vespel

 

Vespel offers ease of machining and tight tolerances due to its inherent mechanical strength, stiffness and dimensional stability. Machining Vespel isn’t too different from machining metals as a result of this; pretend you’re machining brass. Unlike metal, though, Vespel (like all thermoplastics) will deform if you hold it too tightly.

We generally recommend Tungsten Carbide Alloy Tooling, although we recommend diamond tooling for large volume runs or work requiring close tolerances. Be wary of overheating Vespel when you machine it. It shouldn’t become so hot that you can’t grasp it with your bare hands.

We also suggest non-aromatic, air-based coolants to achieve optimum surface finishes and close tolerances. Coolants have the additional benefit of extending tool life as well.

 

Preventing Contamination

 

Contamination is a serious concern when machining polymer components for technically demanding industries such as aerospace sciences. To ensure the highest level of sanitation down to the sub-molecular level, AIP Precision Machining designs, heat-treats and machines only plastics, with any sub-manufactured metalwork processed outside our facility.

 

Vespel Machining Guide: Supportive Information

DuPont Machining Vespel Guide

Aerospace Market Materials

Energy Sector Materials

Extreme Performance Materials

 

 

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